论文标题

低温光电流光谱揭示的单层MOS2中的激子,Trions和Rydberg状态

Excitons, trions and Rydberg states in monolayer MoS2 revealed by low temperature photocurrent spectroscopy

论文作者

Vaquero, Daniel, Clericò, Vito, Salvador-Sánchez, Juan, Martín-Ramos, Adrián, Díaz, Elena, Domínguez-Adame, Francisco, Meziani, Yahya M., Diez, Enrique, Quereda, Jorge

论文摘要

我们研究了H-BN封装的单层$ \ textrm {MOS} _2 $ phototransistor在低温温度(t = 5 K)下进行的示例转变。光谱呈现出激素峰,线宽低至8 MeV,比早期光电流光谱测量值低一个数量级。我们观察到与中性激子($ \ textrm {x} _ {\ textrm {\ textrm {1S}}^\ textrm {a} $和$ \ textrm {x} _ {\ textrm {\ textrm {1S}}^\ textrm {b} $)的四个光谱特征($ \ textrm {t}^\ textrm {a} $和$ \ textrm {t}^\ textrm {b} $),以及在$ \ textrm {x} _ {x} _ {\ textrm {\ textrm {1S}} urtition的$ \ textrm {x} _ {1S}^$}的$ \ textrm {x} _ $ \ textrm {x}^\ textrm {a} $和$ \ textrm {x}^\ textrm {b} $的Rydberg系列激发态。不同光谱特征的相对强度可以通过施加的栅极和排水源电压来调节,Trions和Rydberg激发态在大栅极电压下变得更加突出。使用有效的质量理论,用于二维过渡金属二藻元中的激子,我们能够准确地拟合测得的光谱线,并明确将它们与相应的rydberg状态相关联。拟合还使我们能够确定单层$ \ textrm {mos} _2 $的准粒子带量和旋转轨道拆分,以及$ \ textrm {x}^\ textrm {x}^\ textrm {a} $ {a} $和$ \ \ \ \ \ \ \ \ textrm {x}}^textrm {x}^\ textrm {x}^\ textrm {x}^}^\ textrm {

We investigate excitonic transitions in a h-BN encapsulated monolayer $\textrm{MoS}_2$ phototransistor by photocurrent spectroscopy at cryogenic temperature (T = 5 K). The spectra presents excitonic peaks with linewidths as low as 8 meV, one order of magnitude lower than in earlier photocurrent spectroscopy measurements. We observe four spectral features corresponding to the ground states of neutral excitons ($\textrm{X}_{\textrm{1s}}^\textrm{A}$ and $\textrm{X}_{\textrm{1s}}^\textrm{B}$) and charged trions ($\textrm{T}^\textrm{A}$ and $\textrm{T}^\textrm{B}$) as well as up to eight additional spectral lines at energies above the $\textrm{X}_{\textrm{1s}}^\textrm{B}$ transition, which we attribute to the Rydberg series of excited states of $\textrm{X}^\textrm{A}$ and $\textrm{X}^\textrm{B}$. The relative intensities of the different spectral features can be tuned by the applied gate and drain-source voltages, with trions and Rydberg excited states becoming more prominent at large gate voltages. Using an effective-mass theory for excitons in two-dimensional transition-metal dichalcogenides we are able to accurately fit the measured spectral lines and unambiguously associate them with their corresponding Rydberg states. The fit also allows us to determine the quasiparticle bandgap and spin-orbit splitting of monolayer $\textrm{MoS}_2$, as well as the exciton binding energies of $\textrm{X}^\textrm{A}$ and $\textrm{X}^\textrm{B}$.

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