论文标题
建模锂离子电池中的电极异质性:单峰和双峰粒度分布
Modelling electrode heterogeneity in lithium-ion batteries: unimodal and bimodal particle-size distributions
论文作者
论文摘要
在锂离子电池的数学模型中,高度异质的多孔电极经常被近似为包含均匀尺寸的球形颗粒,当假定电解质中的传输速度快速时,导致通常使用的单粒子模型(SPM)。在这里,电极异质性是通过将其扩展到粒径分布来建模的。考虑了单峰和双峰粒度分布(PSD)。对于单峰PSD,研究了分布对细胞动力学的扩散的影响,并在评估的SPM近似时选择有效的颗粒半径。渐近技术用于得出对SPM的校正,对狭窄但现实的PSD有效。另外,可以在事后有效地计算出所有粒子的异质内部状态(例如,在降解时相关)。对于双峰PSD,结果通过双粒子模型(DPM)很好地近似,其中一个大小代表每个模式。用双峰PSD磷酸锂的结果表明,DPM在放电曲线中捕获了实验性观察到的双倍plateau,这完全归因于双峰性。
In mathematical models of lithium-ion batteries, the highly heterogeneous porous electrodes are frequently approximated as comprising spherical particles of uniform size, leading to the commonly-used single-particle model (SPM) when transport in the electrolyte is assumed to be fast. Here electrode heterogeneity is modelled by extending this to a distribution of particle sizes. Unimodal and bimodal particle-size distributions (PSD) are considered. For a unimodal PSD, the effect of the spread of the distribution on the cell dynamics is investigated, and choice of effective particle radius when approximating by an SPM assessed. Asymptotic techniques are used to derive a correction to the SPM valid for narrow, but realistic, PSDs. In addition, it is shown that the heterogeneous internal states of all particles (relevant when modelling degradation, for example) can be efficiently computed after-the-fact. For a bimodal PSD, the results are well approximated by a double-particle model (DPM), with one size representing each mode. Results for lithium iron phosphate with a bimodal PSD show that the DPM captures an experimentally-observed double-plateau in the discharge curve, suggesting it is entirely due to bimodality.