论文标题

由自旋循环结构驱动的电子电荷转移

Electronic charge transfer driven by spin cycloidal structure

论文作者

Ishii, Y., Horio, S., Noda, Y., Hiraishi, M., Okabe, H., Miyazaki, M., Takeshita, S., Koda, A., Kojima, K. M., Kadono, R., Sagayama, H., Nakao, H., Murakami, Y., Kimura, H.

论文摘要

MUON自旋旋转和谐振软X射线散射实验在原型多表演rmn2O5上(R = Y,SM)用于证明局部电位位移是由自旋 - 电流(SC)机制驱动的。通过在配体O离子上观察自旋极化来评估局部电动位移,为此,植入的muons用作非常敏感的探针。我们对YMN2O5的结果提供了证据表明,与Mn离子的载体自旋手性(SI X SJ)成比例增加,形成带有MN旋转的自旋环链的O离子的自旋极化增加。这种关系强烈表明O和Mn离子之间的电荷转移是由SC机制驱动的,SC机制导致伴随O自旋极化的铁电性。

Muon spin rotation and resonant soft X-ray scattering experiments on prototype multiferroics RMn2O5 (R = Y, Sm) are used to demonstrate that the local electric displacements are driven by the spin-current (SC) mechanism. Small local electric displacements were evaluated by observing spin polarization at ligand O ions, for which implanted muons served as an extremely sensitive probe. Our results for YMn2O5 provide evidence that the spin polarization of O ions forming a spin cycloid chain with Mn spins increases in proportion to the vector spin chirality (Si x Sj ) of the Mn ions. This relationship strongly indicates that the charge transfer between O and Mn ions is driven by the SC mechanism, which leads to the ferroelectricity accompanying O spin polarization.

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